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UK COSHH Data Sheet Reference

Formaldehyde (Nail Hardener/Keratin Treatment) COSHH Data Sheet UK

A HSE-format UK COSHH data sheet reference for Formaldehyde (Nail Hardener/Keratin Treatment) (also known as Formaldehyde, Formalin, Methanal). Covers workplace exposure limits from HSE EH40/2005, GHS hazard classification, control measures, PPE, storage, spillage and emergency procedures. Use the data here to complete your own COSHH assessment, or generate a workplace-specific PDF in 5 minutes.

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Baseline Risk Rating
High
CAS Number: 50-00-0
Physical Form: Liquid solution, released as gas during heat treatment or application
Common Names: Formaldehyde, Formalin, Methanal, Keratin Smoothing, Brazilian Blowout
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Important noteThis reference summary is compiled from HSE EH40/2005 and publicly available manufacturer Safety Data Sheets. It is not the manufacturer's official SDS for any specific product. Before relying on any COSHH assessment based on this data, cross-check against the SDS supplied with the specific product you use in your workplace. See our methodology page for how we source and verify data.

GHS Hazard Classification

Carcinogen Cat 1B (H350), Mutagen Cat 2 (H341), Acute Toxicity Cat 3 (H301, H311, H331), Skin Corrosive (H314), Skin/Respiratory Sensitiser (H317, H334).

Health Effects

Classified as a human carcinogen. Some keratin smoothing treatments release formaldehyde when heated, exposing stylists to harmful levels. UK HSE has issued warnings about salon exposure. Long-term risks include nasopharyngeal cancer. Immediate risks include severe respiratory irritation, skin burns, and asthma.

Routes of Exposure

  • Inhalation (primary)
  • Skin contact
  • Eye contact

Workplace exposure to Formaldehyde (Nail Hardener/Keratin Treatment) is regulated under the Control of Substances Hazardous to Health Regulations 2002. Employers must reduce occupational exposure to as low as reasonably practicable, following the HSE hierarchy of control.

Recommended Control Measures

Applied in the HSE hierarchy of control order: eliminate, substitute, engineering, administrative, PPE.

  • Prefer formaldehyde-free alternatives - do not use products that release formaldehyde on heating
  • If used, requires local exhaust ventilation and air monitoring
  • Health surveillance for staff mandatory
  • Detailed COSHH assessment required with monitoring records

Recommended PPE

  • Nitrile gloves
  • Respiratory protection (organic vapour cartridge respirator)
  • Eye protection (chemical splash goggles)
  • Full apron

Emergency Procedures

Skin contact: Remove contaminated clothing. Rinse skin with plenty of water. Seek medical attention immediately for chemical burns.
Eye contact: Rinse immediately with water for at least 15 minutes. Get emergency medical attention.
Inhalation: Move to fresh air. Seek medical attention immediately. Can cause delayed respiratory injury.
Ingestion: Do not induce vomiting. Rinse mouth. Get emergency medical attention immediately.
UK emergency: 999. Medical advice: NHS 111. Poisons information for healthcare professionals: TOXBASE.

Data Sources

HSE Carcinogens Regulations; IARC Monograph 100F; UK salon safety warnings; EH40/2005 Table 1

Frequently asked questions

Is a COSHH assessment required for Formaldehyde (Nail Hardener/Keratin Treatment)?

Yes. Any UK employer whose staff work with Formaldehyde (Nail Hardener/Keratin Treatment) must hold a written COSHH assessment under the Control of Substances Hazardous to Health Regulations 2002, Regulation 6. The assessment must be reviewed at least annually and immediately if circumstances change. You can generate one free (watermarked) using our tool.

What is the Workplace Exposure Limit for Formaldehyde (Nail Hardener/Keratin Treatment)?

Workplace Exposure Limits (WELs) for Formaldehyde (Nail Hardener/Keratin Treatment) are published by HSE in EH40/2005. Values come as an 8-hour time-weighted average (TWA) and 15-minute short-term exposure limit (STEL). Where a formal WEL has not been set for this substance, we mark the field as "Not established" and rely on hazard-based controls following the hierarchy of control.

What PPE is needed for Formaldehyde (Nail Hardener/Keratin Treatment)?

The recommended PPE typically includes: Nitrile gloves; Respiratory protection (organic vapour cartridge respirator); Eye protection (chemical splash goggles); Full apron. Actual PPE requirements depend on how Formaldehyde (Nail Hardener/Keratin Treatment) is used in your specific workplace, how often, and existing engineering controls. Your COSHH assessment should specify PPE only after engineering and administrative controls have been considered.

Do I need health surveillance for workers using Formaldehyde (Nail Hardener/Keratin Treatment)?

Health surveillance under COSHH 2002 Regulation 10 is required for substances that are respiratory sensitisers, skin sensitisers, or carcinogens where exposure is significant. If Formaldehyde (Nail Hardener/Keratin Treatment) appears on the HSE health surveillance list for your industry, workers with regular exposure should have baseline and annual monitoring.

Generate a workplace-specific COSHH assessment for Formaldehyde (Nail Hardener/Keratin Treatment)

Answer 6 quick questions about your workplace and download a 7-page HSE-format PDF. First one is free (watermarked). Paid bundles from £29 for 10 clean PDFs.

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References

  1. Control of Substances Hazardous to Health Regulations 2002 (SI 2002/2677), UK legislation.gov.uk
  2. HSE EH40/2005 Workplace Exposure Limits, Health and Safety Executive
  3. COSHH basics: What you need to know, HSE
  4. COSHH essentials, control guidance for employers, HSE
  5. L5, Approved Code of Practice and guidance, HSE